Search results for "vis photo polymerization"

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Influence of a Crosslinker Containing an Azo Group on the Actuation Properties of a Photoactuating LCE System

2016

Photoactuating liquid crystalline elastomers (LCE) are promising candidates for an application as artificial muscles in microdevices. In this work, we demonstrate that by optimizing (1) the illumination conditions and (2) the mixture of azo monomer and azo crosslinker, thick films of an all-azo LCE can be prepared, which show a strong length change without bending during photoactuation. This becomes possible by working with white light (about 440 nm), whose absorption is low, leading to a large penetration depth. By adding an azo crosslinker to a previously prepared system, several improvements of the actuation properties—like a stronger photoactuation at lower operational temperatures—coul…

Materials sciencePolymers and Plasticsvis photo polymerizationazo02 engineering and technology010402 general chemistryElastomer01 natural sciencesArticleIsothermal processlcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryPolymer chemistryphotoactuationliquid crystalline elastomersIrradiationPenetration depthAbsorption (electromagnetic radiation)crosslinkerlight-responsiveactuatorpolymer filmGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesliquid crystalline networkPhotopolymerMonomerChemical engineeringchemistryliquid crystalline elastomers; photoactuation; polymer film; light-responsive; azo; crosslinker; actuator; vis photo polymerization; liquid crystalline networkArtificial muscle0210 nano-technologyPolymers
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